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- W2018776005 abstract "The intensities from nearly stoichiometric powder samples are measurrd using CuKα radiation and they are corrected for surface roughness and preferred orientation effects. The electron distributions of the atoms are analysed in terms of cubic harmonic expansions. It is found that, in comparison with free-atom model, the charge density of tho titanium atom is extended radially and the carbon atom is contracted. Non-spherical components of lowest orders are found for both constituent atoms and they indicate directional redistribution of charge density during formation of bonds.Die Intensitaten der Beugungsmaxima an Pulverproben fast stochiometrischen Titaniumkarbids werden unter Anwendung von CuKα Strahlung gemessen und auf Texturcffekte und die Grobheit der Oberflache korrigiert. Die Elektronenverteilung wird aufgrund einer Reihenentwicklung In kubische Kugelfunktionen untersucht. Die Untersuchung zeigt, das sich Im Vergleich zufreien Ato-men die Verteilung der Ladungsdichte sowohl bei Ti- als auch bei C-Atomen verandert. Die La-dungsdichte des Ti-Atoms ist radial erweitert und die des C-Atoms verengt. Die nicht-spharischen Komponenten niedrigster Ordnung, die die Umvertcilung der Ladungsdichte charakterisieren, werden fur beide Atome bestimmt." @default.
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- W2018776005 title "X-Ray Diffraction Study of Charge Distribution in Titanium Carbide" @default.
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- W2018776005 doi "https://doi.org/10.1002/pssa.2210810121" @default.
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