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• W2018777619 startingPage "624" @default.
• W2018777619 abstract "Carbon dioxide in the liquid and supercritical fluid states is useful as a replacement for toxic organic solvents. However, nonvolatile hydrophilic substances such as proteins, ions, and most catalysts are insoluble. This limitation was overcome by the formation of aqueous microemulsion droplets in a carbon dioxide-continuous phase with a nontoxic ammonium carboxylate perfluoropolyether surfactant. Several spectroscopic techniques consistently indicated that the properties of the droplets approach those of bulk water. The protein bovine serum albumin (BSA) with a molecular weight of 67,000 is soluble in this microemulsion and experiences an environment similar to that of native BSA in buffer." @default.
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• W2018777619 date "1996-02-02" @default.
• W2018777619 modified "2023-09-30" @default.
• W2018777619 title "Water-in-Carbon Dioxide Microemulsions: An Environment for Hydrophiles Including Proteins" @default.
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• W2018777619 doi "https://doi.org/10.1126/science.271.5249.624" @default.
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