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• W2018791706 abstract "An efficient synthesis of the tetracyclic steroid core, 19, of rhodexin A and sarmentogenin is reported. An initial inverse-electron-demand Diels−Alder reaction of the acyldiene 6 with the silyl enol ether 7a gave the cycloadduct 8 with the required four contiguous stereocenters in a single step. This compound was then transformed into the methylated enedione 13 which afforded after a reductive alkylation and annulation sequence the tetracycle 19." @default.
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• W2018791706 date "2008-07-22" @default.
• W2018791706 modified "2023-09-23" @default.
• W2018791706 title "Preparation of a Functionalized Tetracyclic Intermediate for the Synthesis of Rhodexin A" @default.
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• W2018791706 doi "https://doi.org/10.1021/ol801426z" @default.
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