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• W2018804296 abstract "(Hemi)fluorinated hydrophobic chains have been found to minimize the denaturating propensity of surfactants toward membrane proteins. The work reported herein deals with the synthesis of a new series of non-ionic glucose-based surfactants endowed with a hybrid hemifluorocarbon chain. The convergent synthesis is based on a one-pot reduction/alkylation of hemifluorinated thioacetate and glucosylated trishydroxymethyl acrylamidomethane using NaBH4 in methanol. This “mild” alkylation was studied in order to improve yields and to pass up the use of an excess of commercially unavailable hemifluorinated thiols. The physical-chemical properties in aqueous solution of this novel series were studied by surface tension measurement and dynamic light scattering (DLS), as well as their behavior upon reverse-phase chromatography, and were compared with those of their hydrogenated and perfluorinated analogues. The atypical effect of the additional ethyl tip to the fluorinated chain was demonstrated by higher critical micellar concentration values and abnormal hydrophobicities measured by reverse-phase chromatography. Moreover, according to Israelachvili’s concept, DLS studies showed that surfactants bearing bulkier polar head self-assemble into small and well-defined aggregates, suggesting the formation of spherical micelles rather than the cylindrical ones usually observed with classical fluorinated surfactants." @default.
• W2018804296 created "2016-06-24" @default.
• W2018804296 creator A5004074755 @default.
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• W2018804296 date "2008-09-30" @default.
• W2018804296 modified "2023-09-23" @default.
• W2018804296 title "Glucose-Based Surfactants with Hydrogenated, Fluorinated, or Hemifluorinated Tails: Synthesis and Comparative Physical-Chemical Characterization" @default.
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• W2018804296 doi "https://doi.org/10.1021/jo801379e" @default.
• W2018804296 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/18823145" @default.
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