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• W2018876105 abstract "Various hydrotalcite based catalysts were prepared for testing for the catalytic decomposition of N2O. CoAl, NiAl, Co/PdAl, Co/RhAl, and Co/MgAL substituted hydrotalcites and CoLaAl hydroxides offer very good activity at modest temperatures. Precalcination of these materials at ca. 450–500°C, which destroys the hydrotalcite phase, is necessary for optimum activity and life. For Co substituted hydrotalcites, the optimal ratio of Co/Al is 3.0. The temperature for 50% conversion of N2O of these calcined cobalt hydrotalcites is ca. 75°C lower than for the previous highly active Co-ZSM-5. These calcined cobalt hydrotalcite materials display sustained life at temperatures in excess of 670°C in an O2 rich, wet stream with high levels of N2O [10%]. Excess O2 does not seriously impact N2O decomposition, but the combination of both water vapor and O2 does reduce activity by ca. 50%." @default.
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• W2018876105 date "1996-01-01" @default.
• W2018876105 modified "2023-10-01" @default.
• W2018876105 title "Calcined hydrotalcites for the catalytic decomposition of N2O in simulated process streams" @default.
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• W2018876105 doi "https://doi.org/10.1016/0926-3373(95)00048-8" @default.
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