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- W2018907632 abstract "The carbonylation and cyclization of N-alkylallylamines to γ-butyrolactams is efficiently achieved by use of RhCl3 · 3H2OPPh3 or RhCl(CO)(PPh3)2 as catalyst precursors under mild conditions (70°C, 10 bar) when COH2 (4:1) mixtures are used instead of pure CO. Mechanistic studies on the Rh and the analogous Ir system allowed the deduction of a major catalytic cycle in which the active species is RhCl(CO)2(PPh3)2 and the role of H2 is the decomposition of an intermediate containing a coordinated carbamoyl fragment derived from a nucleophilic attack of the amine to a coordinated CO." @default.
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- W2018907632 title "The mechanism of the mild rhodium-catalyzed carbonylation and cyclization of N-alkylallylamines to γ-butyrolactams under COH2" @default.
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