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- W2018921568 abstract "Abstract The high‐pressure behavior of new supramolecular compound based on arsenic vanadates formulated as [H 2 As 6 V 15 O 42 (H 2 O)][Co(H 2 O) 6 ] 2 .2H 2 O is investigated by Raman spectroscopy using a diamond anvil cell up to 21GPa. A reversible pressure‐induced phase transition was observed at a pressure above 8.3 GPa. Upon compression, the intensity of modes at lower‐frequency from 100‐600 cm ‐1 V 1 , V 2 , V 3 , V 4 , softens and vanishes at about 8.3 GPa. Also, the high‐frequency v 7 (937cm ‐1 ) disappears at about 8.3 GPa. The reversible transition may be due to both the extinct of vanadyl(V=O) double bonds in VO 5 pyramids and the changes in the AsO 3 network under pressure. (© 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)" @default.
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- W2018921568 date "2011-04-07" @default.
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- W2018921568 title "Compressibility and vibration modes of the supramolecular compound assembly from arsenic vanadates and [Co(H2O)6]2+ cations" @default.
- W2018921568 doi "https://doi.org/10.1002/pssc.201000861" @default.
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