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- W2018922015 abstract "The B2Σ+ → X2Σ+ (0–1, 2, 3, 4 progression) electronic transition of 12C17O+ was first observed and analyzed by Szajna and Ke¸pa [Spectrochim. Acta A 65 (2006) 1014–1020]. We have now extended our previous studies. The use of high resolution conventional spectroscopic techniques has allowed first rotational analysis of the 1–2, 1–3, 1–4 and 1–5 bands of the first negative system in the 37,000–43,000 cm−1 spectral region. Approximately 500 transition wavenumbers were measured with an estimated accuracy of 0.005 cm−1. The present data were combined with the previous measurements to yield an improved set of molecular constants for the B2Σ+(v′ = 0, 1) and X2Σ+(v″ = 1, 2, 3, 4, 5). The v′ = 1 and v″ = 5 vibrational levels were observed for the first time and the main molecular constants are (in cm−1, one standard deviation in parentheses) B2Σ+X2Σ+B1 = 1.710792(20)B5 = 1.825694(23)D1 = 7.799(15) × 10−6D5 = 6.085(21) × 10−6γ1 = 1.9491(37) × 10−2γ5 = [8.381] × 10−3 The principal equilibrium molecular constants for the B2Σ+ and X2Σ+ states have also been derived and the vibrational terms values for the ground and excited states have been calculated." @default.
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- W2018922015 date "2006-11-01" @default.
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- W2018922015 title "The 1-v″ bands progression of the B2Σ+→X2Σ+ system of 12C17O+" @default.
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