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• W2018924881 abstract "Abstract The 2-hexyl radical, CH3CH(CH2)3CH3, has been produced selectively by γ-irradiation in an n-hexane-d14 crystal containing 0.25% n-hexane. The full coupling tensors of the α-, β- and methyl-protons have been obtained and are found to have the principal values (36.1, 20.5, 12.1), (36.1, 32.4, 32.4) and (27.6, 24.1, 23.8) G respectively. It was possible to resolve the γ-proton coupling in some directions by virtue of the narrow linewidth in the deuterated crystal and the principal values were estimated to be (2.2, −0.5, −0.5) G with an isotropic coupling of ca. +0.45 G. It is concluded that a rotation around the C2C3 bond of roughly 180° occurs when the 2-hexyl radical is formed from the parent molecule." @default.
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• W2018924881 date "1975-05-01" @default.
• W2018924881 modified "2023-09-27" @default.
• W2018924881 title "Anisotropic γ-proton coupling and α-, β- and methyl-proton hyperfine coupling tensors in the 2-hexyl radical" @default.
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• W2018924881 doi "https://doi.org/10.1016/0009-2614(75)85233-x" @default.
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