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- W201893178 abstract "Abstract Active charcoals have been treated with chlorine at 450°C as well as with sulfur vapour at 600°C. There is considerable chemisorption of chlorine, whereas sulfur is not only chemisorbed. A considerable part of the bound sulfur is present in the form of polymer sulfur which cannot convert to soluble α-sulfur due to steric hindrance. After these reactions, the micropore volume accessible to nitrogen at 77 K was reduced. Removal of the chemisorbed chlorine with H 2 at 600°C or with NH 3 at 300 - 600°C opened the closed pores again. Thermal depolymerization removed only polymer sulfur from the mesopores, while the micropores remained closed by chemisorbed sulfur. There was indication of activated diffusion of N 2 within chlorinated active charcoals." @default.
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- W201893178 date "1982-01-01" @default.
- W201893178 modified "2023-10-14" @default.
- W201893178 title "Blocking of pores in porous carbons by chemisorption" @default.
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- W201893178 doi "https://doi.org/10.1016/s0167-2991(09)61356-2" @default.
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