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- W2018954632 abstract "In this paper, we used two fluorine-containing ligands of 2-(2-fluorophenyl)benzo[d]thiazole (F-BT) and 1,1,1,5,5,5-hexafluoropentane-2,4-dione (acac-F6) to construct an Ir complex of Ir(acac-F6)(F-BT)2. The single crystal of Ir(acac-F6)(F-BT)2 is observed, which confirms its identity. Ir(acac-F6)(F-BT)2 single crystal belongs to monoclinic system with two molecules in each unit cell. Theoretical calculation is performed on Ir(acac-F6)(F-BT)2 to investigate its electronic nature, which suggests that the first electronic transition owns a mixed character of metal-to-ligand-charge-transfer and ligand-to-ligand-charge-transfer. We select a polymer matrix of poly(vinylpyrrolidone) (PVP) to explore the photophysical property of Ir(acac-F6)(F-BT)2 within microfibers. Results indicate that the photophysical performances of Ir(acac-F6)(F-BT)2 within microfibers are improved compared with those of Ir(acac-F6)(F-BT)2 powder, including microfiber sample's higher emission energy, longer excited state lifetime, and better photostability." @default.
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- W2018954632 date "2012-02-01" @default.
- W2018954632 modified "2023-09-23" @default.
- W2018954632 title "Characterization and emissive property of microfibers doped with fluorine functionalized iridium complex" @default.
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- W2018954632 doi "https://doi.org/10.1016/j.jlumin.2011.09.015" @default.
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