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• W2019007515 abstract "Molecular electrocatalysts for H2 evolution are usually studied under various conditions (solvent and proton sources) that prevent direct comparison of their performances. We provide here a rational method for such a benchmark based on (i) the recent analysis of the current-potential response for two-electron-two-step mechanisms and (ii) the derivation of catalytic Tafel plots reflecting the interdependency of turnover frequency and overpotential based on the intrinsic properties of the catalyst, independent of contingent factors such as cell characteristics. Such a methodology is exemplified on a series of molecular catalysts among the most efficient in the recent literature." @default.
• W2019007515 created "2016-06-24" @default.
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• W2019007515 date "2014-08-07" @default.
• W2019007515 modified "2023-10-17" @default.
• W2019007515 title "Toward the rational benchmarking of homogeneous H₂-evolving catalysts" @default.
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• W2019007515 doi "https://doi.org/10.1039/c4ee01709a" @default.
• W2019007515 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/4530013" @default.
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