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- W2019015078 abstract "Electrochemical oxidation and reduction potentials for large alternant hydrocarbon ions in acetonitrile have been measured, together with the real potential of the silver ion in this solvent. These results, combined with the recently determined ionisation potentials and electron affinities of the hydrocarbons were used to calculate the differential real solvation energies of the anions and cations. It is expected that the difference of ‘chemical’ solvation energy of the anion and cation of these large alternant hydrocarbon ions should be close to zero. This is shown to be substantially correct and the difference in the values of the differential real potential for the anion and cation is therefore identified with the surface potential of the pure solvent." @default.
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- W2019015078 date "1965-11-01" @default.
- W2019015078 modified "2023-10-17" @default.
- W2019015078 title "The real solvation energies of hydrocarbon ions in acetonitrile and the surface potential of acetonitrile" @default.
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- W2019015078 doi "https://doi.org/10.1016/0022-0728(65)80038-9" @default.
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