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- W2019015813 abstract "The question raised in the title was answered. (3R, 3′S)-meso-Zeaxanthin was submitted to iodine catalyzed photochemical stereoisomerisation. The enantiomeric (9Z) and (9′Z) geometrical isomers were isolated by semipreparative HPLC and separated as diastereomeric dicarbamates on a chiral column only. Cleavage of the carbamate could not be effected. CD-Spectra of (1″S, 1″S)- and (1″R, 1″R)-dicarbamates of geometrical isomers of (3R, 3′R)- and (3R, 3′S)-meso-zeaxanthin were systematically studied and the contribution from the carbamate moieties revealed. It was concluded that (9Z, 3R, 3′S)-“meso”-zeaxanthin, in spite of having no symmetry elements, is optically inactive. The result has been rationalised in line with the current hypothesis on the origin of carotenoid CD spectra. Chirality 13:224–229, 2001. © 2001 Wiley-Liss, Inc." @default.
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- W2019015813 date "2001-01-01" @default.
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- W2019015813 title "Is (9Z)-“meso”-zeaxanthin optically active?" @default.
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- W2019015813 doi "https://doi.org/10.1002/chir.1023" @default.
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