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- W2019040650 abstract "(R)-(+)-Paraconic acid 4, (S)-(−)-terebic acid 6 and their corresponding methyl and ethyl esters having ee’s ranging from 60% to 92% were obtained by enzymatic resolution of their racemates. The enzymatic resolution of racemic ethyl γ-methylparaconates 14a and 14b allowed the isolation of the unreacted ester (2R,3R)-(+)-14a and that of the lactonic acid (2S,3R)-(−)-5b with 80% and 93% ee, respectively, the former by the use of Horse liver acetone powder (HLAP), the latter using α-chymotrypsin (α-CT). The enantiomeric ethyl (2S,3S)-(−)-14a and (2S,3R)-(−)-14b, both with >99% ee, were obtained by baker’s yeast reduction of diethyl acetylsuccinate." @default.
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- W2019040650 date "2004-02-01" @default.
- W2019040650 modified "2023-09-26" @default.
- W2019040650 title "Chemoenzymatic synthesis of enantioenriched 5-oxo-tetrahydro-3-furancarboxylic acid derivatives" @default.
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- W2019040650 doi "https://doi.org/10.1016/j.tetasy.2004.01.001" @default.
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