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- W2019053140 abstract "1-Alkynyl ethers of the type R-C≡C-OR′ (R = H or alkyl and R′ = alkyl) were converted by addition of phosgene into β-alkoxy-β-chloroethene carbonic chlorides RO-CCl = CR-CO-Cl (II). From the adducts some amides were prepared. Hexachloroacetone and chloral reacted with ethoxyethyne without a catalyst to (CCl3)2CCH-COOC2H5 (I) and CCl3CHCHCOOC2H5 respectively. Sulfur dichloride already adds on to ethoxyethyne at a low temperature, forming bis(2-ethoxy-2-chlorovinyl) sulfide (VIII), which upon alcoholysis yields bis(ethoxycarbonylmethyl) sulfide (IX)." @default.
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- W2019053140 date "1966-01-01" @default.
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- W2019053140 title "Chemistry of acetylenic ethers 81: synthesis of β-alkoxy-β-chloroacrylic chlorides by addition of phosgene to 1-alkynyl ethers" @default.
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- W2019053140 doi "https://doi.org/10.1002/recl.19660850605" @default.
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