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• W2019063434 endingPage "16665" @default.
• W2019063434 startingPage "16659" @default.
• W2019063434 abstract "The present work reports a new mononuclear Dy(III) complex [Dy(acac)3(dppn)]·C2H5OH (1) (acac = acetylacetone, dppn = benzo[i]dipyrido-[3, 2-a:2',3'-c]phenazine). X-ray crystallography analysis reveals that compound 1 is a discrete molecular complex and the Dy(III) center lies in a square-antiprism coordination environment. Furthermore, complex 1 shows single-ion magnet (SIM) behavior. Compared to the reported complexes [Dy(dppz)(acac)3]·CH3OH, [Dy(dpq)(acac)3] and [Dy(phen)(acac)3], complex 1 exhibits a different energy barrier, which might be raised from the different coordination environment caused by the different auxiliary co-ligand dppn. The energy barrier variations of these Dy(III)-complexes are consistent with their square antiprism structural features." @default.
• W2019063434 created "2016-06-24" @default.
• W2019063434 creator A5003927896 @default.
• W2019063434 creator A5026920281 @default.
• W2019063434 creator A5045918224 @default.
• W2019063434 creator A5051991228 @default.
• W2019063434 date "2014-01-01" @default.
• W2019063434 modified "2023-09-30" @default.
• W2019063434 title "[Dy(acac)₃(dppn)]·C₂H₅OH: construction of a single-ion magnet based on the square-antiprism dysprosium(<scp>iii</scp>) ion" @default.
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• W2019063434 doi "https://doi.org/10.1039/c4dt01956c" @default.
• W2019063434 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25273897" @default.
• W2019063434 hasPublicationYear "2014" @default.
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