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- W2019067515 abstract "A challenging direct asymmetric hydrogenation of (E)-2-oxo-4-arylbut-3-enoic acids to give 2-hydroxy-4-arylbutanoic acids (85.4−91.8% ee) was achieved with a Ru catalyst based on SunPhos as the chiral ligand. Further investigation of the reaction revealed that partial isomerization of 2-hydroxy-4-arylbutenoic acids was involved in the hydrogenation process. Employing the reaction conditions to the hydrogenation of 2-oxo-4-phenylbutanoic acid resulted in better enantioselectivity (91.8% ee) and efficiency (TON = 2000, TOF = 200 h−1), which offers a useful method for the synthesis of a common intermediate for ACE inhibitors." @default.
- W2019067515 created "2016-06-24" @default.
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- W2019067515 creator A5084756878 @default.
- W2019067515 date "2010-08-11" @default.
- W2019067515 modified "2023-10-16" @default.
- W2019067515 title "Direct Asymmetric Hydrogenation of 2-Oxo-4-arylbut-3-enoic Acids" @default.
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- W2019067515 doi "https://doi.org/10.1021/jo101084t" @default.
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