Matches in SemOpenAlex for { <https://semopenalex.org/work/W2019072480> ?p ?o ?g. }
Showing items 1 to 98 of
98
with 100 items per page.
- W2019072480 endingPage "1815" @default.
- W2019072480 startingPage "1807" @default.
- W2019072480 abstract "Syntheses of Ph2Pb(dmit) (3), [Q] [Ph2Pb(dmit)I] (5, Q = NEt4 or 1,4-Me2-pyridinium), (Ph3Pb)2(dmit) (4) and Pb(dmit) (6) are reported [H2-dmit = 4,5-dimercapto-1,3-dithiole-2-thione]. Compound 3 was produced from Ph2Pb(OAc)2 and [NEt4]2[Zn (dmit)2], while 4 was obtained from Ph3PbOAc and either Na2(dmit) or [NEt4]2[Zn(dmit)2]. The ionic species, 5, were obtained by addition of [Q] I to 3 (eg. for Q = 1,4-Me2-pyridinium) or from reaction of Ph2PbI2 with [NEt4]2[Zn(dmit)2]. Reaction of either Pb(OAc)2 or Pb(NO3)2 with [NEt4]2[Zn(dmit)2] produced 6. NMR spectra, including the solid state spectra for 3, have been obtained. X-ray crystallography revealed 4 to be a monomeric compound with each Pb atom having a distorted tetrahedral geometry. The CPbS bond angles are less and the CPbC bond angles greater than ideal tetrahedral angles. The dmit ligand is effectively inserted between two phenyl rings of different Ph3Pb groups in 4, with short non-bonded CC and CS distances of 3.4–3.7 Å. Cyctic voltammetric studies of 3 and of 4 in DMF have also been carried out." @default.
- W2019072480 created "2016-06-24" @default.
- W2019072480 creator A5005373361 @default.
- W2019072480 creator A5006725512 @default.
- W2019072480 creator A5011754868 @default.
- W2019072480 creator A5019891889 @default.
- W2019072480 creator A5023388577 @default.
- W2019072480 creator A5042299953 @default.
- W2019072480 creator A5043407482 @default.
- W2019072480 date "1996-06-01" @default.
- W2019072480 modified "2023-10-12" @default.
- W2019072480 title "Syntheses and properties of the lead 1,3-dithiole-2-thione-4,5-dithiolate (dmit) compounds: Ph2Pb(dmit), [Q] [Ph2Pb(dmit) I] [Q = NEt4 or 1,4-Me2-pyridinium], (Ph3Pb)2 (dmit) and Pb(dmit)" @default.
- W2019072480 cites W1518402923 @default.
- W2019072480 cites W1596558658 @default.
- W2019072480 cites W1977243060 @default.
- W2019072480 cites W1977773016 @default.
- W2019072480 cites W1979813023 @default.
- W2019072480 cites W1985764311 @default.
- W2019072480 cites W1987759830 @default.
- W2019072480 cites W1994395973 @default.
- W2019072480 cites W1996974381 @default.
- W2019072480 cites W1997570728 @default.
- W2019072480 cites W2004325064 @default.
- W2019072480 cites W2016250571 @default.
- W2019072480 cites W2020091610 @default.
- W2019072480 cites W2024606785 @default.
- W2019072480 cites W2030764587 @default.
- W2019072480 cites W2041732463 @default.
- W2019072480 cites W2055811516 @default.
- W2019072480 cites W2060789566 @default.
- W2019072480 cites W2076338057 @default.
- W2019072480 cites W2086145085 @default.
- W2019072480 cites W2092502187 @default.
- W2019072480 cites W2150029448 @default.
- W2019072480 cites W2326713974 @default.
- W2019072480 cites W3137483206 @default.
- W2019072480 doi "https://doi.org/10.1016/0277-5387(95)00433-5" @default.
- W2019072480 hasPublicationYear "1996" @default.
- W2019072480 type Work @default.
- W2019072480 sameAs 2019072480 @default.
- W2019072480 citedByCount "15" @default.
- W2019072480 countsByYear W20190724802015 @default.
- W2019072480 countsByYear W20190724802021 @default.
- W2019072480 crossrefType "journal-article" @default.
- W2019072480 hasAuthorship W2019072480A5005373361 @default.
- W2019072480 hasAuthorship W2019072480A5006725512 @default.
- W2019072480 hasAuthorship W2019072480A5011754868 @default.
- W2019072480 hasAuthorship W2019072480A5019891889 @default.
- W2019072480 hasAuthorship W2019072480A5023388577 @default.
- W2019072480 hasAuthorship W2019072480A5042299953 @default.
- W2019072480 hasAuthorship W2019072480A5043407482 @default.
- W2019072480 hasConcept C116569031 @default.
- W2019072480 hasConcept C145148216 @default.
- W2019072480 hasConcept C149635348 @default.
- W2019072480 hasConcept C155647269 @default.
- W2019072480 hasConcept C170493617 @default.
- W2019072480 hasConcept C178790620 @default.
- W2019072480 hasConcept C185592680 @default.
- W2019072480 hasConcept C2182769 @default.
- W2019072480 hasConcept C2777221202 @default.
- W2019072480 hasConcept C41008148 @default.
- W2019072480 hasConcept C55493867 @default.
- W2019072480 hasConcept C58312451 @default.
- W2019072480 hasConcept C8010536 @default.
- W2019072480 hasConceptScore W2019072480C116569031 @default.
- W2019072480 hasConceptScore W2019072480C145148216 @default.
- W2019072480 hasConceptScore W2019072480C149635348 @default.
- W2019072480 hasConceptScore W2019072480C155647269 @default.
- W2019072480 hasConceptScore W2019072480C170493617 @default.
- W2019072480 hasConceptScore W2019072480C178790620 @default.
- W2019072480 hasConceptScore W2019072480C185592680 @default.
- W2019072480 hasConceptScore W2019072480C2182769 @default.
- W2019072480 hasConceptScore W2019072480C2777221202 @default.
- W2019072480 hasConceptScore W2019072480C41008148 @default.
- W2019072480 hasConceptScore W2019072480C55493867 @default.
- W2019072480 hasConceptScore W2019072480C58312451 @default.
- W2019072480 hasConceptScore W2019072480C8010536 @default.
- W2019072480 hasIssue "11" @default.
- W2019072480 hasLocation W20190724801 @default.
- W2019072480 hasOpenAccess W2019072480 @default.
- W2019072480 hasPrimaryLocation W20190724801 @default.
- W2019072480 hasRelatedWork W1995380826 @default.
- W2019072480 hasRelatedWork W1998093500 @default.
- W2019072480 hasRelatedWork W2010476631 @default.
- W2019072480 hasRelatedWork W2022179207 @default.
- W2019072480 hasRelatedWork W2048162547 @default.
- W2019072480 hasRelatedWork W2092893301 @default.
- W2019072480 hasRelatedWork W2156834779 @default.
- W2019072480 hasRelatedWork W2171032981 @default.
- W2019072480 hasRelatedWork W2325999596 @default.
- W2019072480 hasRelatedWork W2952073381 @default.
- W2019072480 hasVolume "15" @default.
- W2019072480 isParatext "false" @default.
- W2019072480 isRetracted "false" @default.
- W2019072480 magId "2019072480" @default.
- W2019072480 workType "article" @default.