FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2019078977> ?p ?o ?g. }

• W2019078977 endingPage "134" @default.
• W2019078977 startingPage "125" @default.
• W2019078977 abstract "The addition of carbon donor nucleophiles to (arene)Mn(CO)2L+ (L=CO, P(OPh)3, PMe3), followed by replacement of a CO with NO+, affords monofunctionalized (cyclohexadienyl)Mn(CO)(NO)L+ complexes (12). A study has been made of nucleophilic addition to 12 to yield cyclohexadiene complexes (13). The yield of the reaction of 12 with soft stabilized carbon donors (e.g. NaCH(CO2Et)CN) improves substantially when the ligand LCO is replaced by LP(OPh)3 or PMe3. Hydride donors give good yields of monofunctionalized cyclohexadiene complexes regardless of the nature of L. When L≠CO, significant chiral discrimination takes place and the product is obtained as a mixture of diastereomers. Oxidation of the (cyclohexadiene)Mn(CO)(NO)L complexes with FeCl3 or Me3NO generates the free hydrocarbon ligand as cis-disubstituted cyclohexa-1,3-dienes or cyclohexen-1-ones, the latter resulting from hydrolysis of a methoxy substituent. Hard carbon donors such as LiPh and LiMe attack a CO in 12, ultimately converting to trans-disubstituted cyclohexadienes. This work shows that the manganese- mediated double nucleophilic addition to arenes can be an efficient route to functionalized cyclohexadienes." @default.
• W2019078977 created "2016-06-24" @default.
• W2019078977 creator A5007996922 @default.
• W2019078977 creator A5014981189 @default.
• W2019078977 creator A5018624716 @default.
• W2019078977 creator A5019606787 @default.
• W2019078977 creator A5031481431 @default.
• W2019078977 date "1993-12-01" @default.
• W2019078977 modified "2023-10-03" @default.
• W2019078977 title "Manganese-mediated synthesis of cis-disubstituted cyclohexadienes via double nucleophilic addition to coordinated arenes" @default.
• W2019078977 cites W1494726561 @default.
• W2019078977 cites W1970474300 @default.
• W2019078977 cites W1971014901 @default.
• W2019078977 cites W1971838926 @default.
• W2019078977 cites W1974332363 @default.
• W2019078977 cites W1976578946 @default.
• W2019078977 cites W1996560952 @default.
• W2019078977 cites W2002407345 @default.
• W2019078977 cites W2005500344 @default.
• W2019078977 cites W2008360633 @default.
• W2019078977 cites W2010218604 @default.
• W2019078977 cites W2010444805 @default.
• W2019078977 cites W2013547676 @default.
• W2019078977 cites W2014998911 @default.
• W2019078977 cites W2019475970 @default.
• W2019078977 cites W2022979761 @default.
• W2019078977 cites W2031062622 @default.
• W2019078977 cites W2031332581 @default.
• W2019078977 cites W2033161366 @default.
• W2019078977 cites W2037391603 @default.
• W2019078977 cites W2042960908 @default.
• W2019078977 cites W2047410795 @default.
• W2019078977 cites W2060147405 @default.
• W2019078977 cites W2060653181 @default.
• W2019078977 cites W2061291933 @default.
• W2019078977 cites W2061517045 @default.
• W2019078977 cites W2062231864 @default.
• W2019078977 cites W2065164672 @default.
• W2019078977 cites W2074761653 @default.
• W2019078977 cites W2075530976 @default.
• W2019078977 cites W2080898792 @default.
• W2019078977 cites W2091104376 @default.
• W2019078977 cites W2094430659 @default.
• W2019078977 cites W2159351247 @default.
• W2019078977 cites W2604423474 @default.
• W2019078977 cites W2949666287 @default.
• W2019078977 cites W2951738707 @default.
• W2019078977 cites W2952486165 @default.
• W2019078977 cites W2952616655 @default.
• W2019078977 cites W3004480188 @default.
• W2019078977 cites W1983789374 @default.
• W2019078977 cites W1991748350 @default.
• W2019078977 doi "https://doi.org/10.1016/s0020-1693(00)87533-7" @default.
• W2019078977 hasPublicationYear "1993" @default.
• W2019078977 type Work @default.
• W2019078977 sameAs 2019078977 @default.
• W2019078977 citedByCount "29" @default.
• W2019078977 countsByYear W20190789772012 @default.
• W2019078977 countsByYear W20190789772021 @default.
• W2019078977 crossrefType "journal-article" @default.
• W2019078977 hasAuthorship W2019078977A5007996922 @default.
• W2019078977 hasAuthorship W2019078977A5014981189 @default.
• W2019078977 hasAuthorship W2019078977A5018624716 @default.
• W2019078977 hasAuthorship W2019078977A5019606787 @default.
• W2019078977 hasAuthorship W2019078977A5031481431 @default.
• W2019078977 hasConcept C104779481 @default.
• W2019078977 hasConcept C116569031 @default.
• W2019078977 hasConcept C134121241 @default.
• W2019078977 hasConcept C138716334 @default.
• W2019078977 hasConcept C140205800 @default.
• W2019078977 hasConcept C155647269 @default.
• W2019078977 hasConcept C159985019 @default.
• W2019078977 hasConcept C161790260 @default.
• W2019078977 hasConcept C170493617 @default.
• W2019078977 hasConcept C178790620 @default.
• W2019078977 hasConcept C178907741 @default.
• W2019078977 hasConcept C185592680 @default.
• W2019078977 hasConcept C191897082 @default.
• W2019078977 hasConcept C192562407 @default.
• W2019078977 hasConcept C20774148 @default.
• W2019078977 hasConcept C2777961443 @default.
• W2019078977 hasConcept C2778689049 @default.
• W2019078977 hasConcept C528890316 @default.
• W2019078977 hasConcept C544153396 @default.
• W2019078977 hasConcept C55493867 @default.
• W2019078977 hasConcept C71240020 @default.
• W2019078977 hasConcept C94412978 @default.
• W2019078977 hasConceptScore W2019078977C104779481 @default.
• W2019078977 hasConceptScore W2019078977C116569031 @default.
• W2019078977 hasConceptScore W2019078977C134121241 @default.
• W2019078977 hasConceptScore W2019078977C138716334 @default.
• W2019078977 hasConceptScore W2019078977C140205800 @default.
• W2019078977 hasConceptScore W2019078977C155647269 @default.
• W2019078977 hasConceptScore W2019078977C159985019 @default.
• W2019078977 hasConceptScore W2019078977C161790260 @default.
• W2019078977 hasConceptScore W2019078977C170493617 @default.
• W2019078977 hasConceptScore W2019078977C178790620 @default.
• W2019078977 hasConceptScore W2019078977C178907741 @default.

• next