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• W2019085655 abstract "Treatment of Cp*TaCl4 with 1 equiv of Li2(R2-dad) in THF afforded Cp*Ta(R2-dad)Cl2 (R = iPr (1), tBu (2)). The chlorido ligands of 1 and 2 reacted smoothly with 2 equiv of LiC⋮CtBu, MeMgI and LiStBu, resulting in Cp*Ta(R2-dad)(C⋮CtBu)2 (R = iPr (3), tBu (4)), Cp*Ta(R2-dad)Me2 (R = iPr (5), tBu (6)), and Cp*Ta(tBu2-dad)(StBu)2 (7), respectively. The X-ray analyses of 1, 3, 4, 5, and 7 have been carried out. In the structures of 1, 3, 4, and 5, the R2-dad ligand is bound to the metal center with a σ2(N,N‘), π(C,C‘)-coordination mode, which opts for a supine conformation with respect to the Cp* group for 1 and 3, while an alternative prone conformation is adopted for 4 and 5. In contrast, the tBu2-dad ligand of 7 assumes an intriguing η2(N,C) coordination geometry. Treatment of 7 in toluene at 80 °C was found to induce C−S bond cleavage of the thiolates generating Cp*Ta(tBu2-dad)(S) (8), in which the dad ligand resumes a σ2, π-coordination geometry with a prone conformation." @default.
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• W2019085655 date "1998-09-01" @default.
• W2019085655 modified "2023-10-03" @default.
• W2019085655 title "Mono(pentamethylcyclopentadienyl)tantalum Complexes Containing a Structurally Versatile Enediamido(2−) Ligand" @default.
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• W2019085655 doi "https://doi.org/10.1021/om980319g" @default.
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