FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2019087718> ?p ?o ?g. }

• W2019087718 endingPage "163" @default.
• W2019087718 startingPage "159" @default.
• W2019087718 abstract "The three-dimensional Cu(II) coordination polymers [Cu(isonicotinate)2][EtOH] (1) and Cu(nicotinate)2 (2) were synthesized by treating copper nitrate with isonicotinic acid and nicotinic acid under hydro(solvo)thermal conditions, respectively. X-ray single-crystal structure determinations reveal that the Cu(II) centers in 1 adopt a slightly distorted square pyramidal geometry, while the Cu(II) centers in 2 exhibit a coordination geometry intermediate between square pyramid and trigonal bipyramid. The Cu(II) centers in 1 and 2 coordinate to both the pyridyl and carboxylate functionalities of the isonicotinate and nicotinate bridging ligands, respectively, to result in complicated 3-D framework structures. Compound 1 exhibits rhombic open channels that are occupied by removable ethanol molecules. Magnetic measurements indicated that 1 is a simple paramagnet with only very weak antiferromagnetic interactions, while 2 exhibits more pronounced antiferromagnetic interactions with J/k = −6.4 K. Crystal data for 1: monoclinic, space group Cc, a = 5.033(1) Å, b = 24.855(5) Å, c = 11.176(2) Å, β = 99.35(3)°, and Z = 4. Crystal data for 2: monoclinic, space group P21/n, a = 10.693(2) Å, b = 9.589(2) Å, c = 12.535(3) Å, β = 112.09(3)°, and Z = 4." @default.
• W2019087718 created "2016-06-24" @default.
• W2019087718 creator A5003570666 @default.
• W2019087718 creator A5019362937 @default.
• W2019087718 creator A5031701288 @default.
• W2019087718 creator A5052171520 @default.
• W2019087718 creator A5057193669 @default.
• W2019087718 date "2001-01-19" @default.
• W2019087718 modified "2023-10-16" @default.
• W2019087718 title "Synthesis, X-ray Structures, and Magnetic Properties of Copper(II) Pyridinecarboxylate Coordination Networks" @default.
• W2019087718 cites W1981563221 @default.
• W2019087718 cites W1985396951 @default.
• W2019087718 cites W1989778917 @default.
• W2019087718 cites W1995709260 @default.
• W2019087718 cites W2009046603 @default.
• W2019087718 cites W2014909360 @default.
• W2019087718 cites W2027525749 @default.
• W2019087718 cites W2036878267 @default.
• W2019087718 cites W2079832683 @default.
• W2019087718 cites W2083059128 @default.
• W2019087718 cites W2084024682 @default.
• W2019087718 cites W2163590606 @default.
• W2019087718 cites W2950580013 @default.
• W2019087718 cites W4248052365 @default.
• W2019087718 doi "https://doi.org/10.1021/cg005519l" @default.
• W2019087718 hasPublicationYear "2001" @default.
• W2019087718 type Work @default.
• W2019087718 sameAs 2019087718 @default.
• W2019087718 citedByCount "98" @default.
• W2019087718 countsByYear W20190877182012 @default.
• W2019087718 countsByYear W20190877182013 @default.
• W2019087718 countsByYear W20190877182014 @default.
• W2019087718 countsByYear W20190877182015 @default.
• W2019087718 countsByYear W20190877182016 @default.
• W2019087718 countsByYear W20190877182017 @default.
• W2019087718 countsByYear W20190877182018 @default.
• W2019087718 countsByYear W20190877182019 @default.
• W2019087718 countsByYear W20190877182020 @default.
• W2019087718 countsByYear W20190877182021 @default.
• W2019087718 countsByYear W20190877182022 @default.
• W2019087718 countsByYear W20190877182023 @default.
• W2019087718 crossrefType "journal-article" @default.
• W2019087718 hasAuthorship W2019087718A5003570666 @default.
• W2019087718 hasAuthorship W2019087718A5019362937 @default.
• W2019087718 hasAuthorship W2019087718A5031701288 @default.
• W2019087718 hasAuthorship W2019087718A5052171520 @default.
• W2019087718 hasAuthorship W2019087718A5057193669 @default.
• W2019087718 hasConcept C111592845 @default.
• W2019087718 hasConcept C112887158 @default.
• W2019087718 hasConcept C115624301 @default.
• W2019087718 hasConcept C121332964 @default.
• W2019087718 hasConcept C155355069 @default.
• W2019087718 hasConcept C16889073 @default.
• W2019087718 hasConcept C170751736 @default.
• W2019087718 hasConcept C178790620 @default.
• W2019087718 hasConcept C185592680 @default.
• W2019087718 hasConcept C194196696 @default.
• W2019087718 hasConcept C200119971 @default.
• W2019087718 hasConcept C26873012 @default.
• W2019087718 hasConcept C2775998212 @default.
• W2019087718 hasConcept C2777854368 @default.
• W2019087718 hasConcept C2778074193 @default.
• W2019087718 hasConcept C32909587 @default.
• W2019087718 hasConcept C544778455 @default.
• W2019087718 hasConcept C61276311 @default.
• W2019087718 hasConcept C71240020 @default.
• W2019087718 hasConcept C8010536 @default.
• W2019087718 hasConcept C92840921 @default.
• W2019087718 hasConceptScore W2019087718C111592845 @default.
• W2019087718 hasConceptScore W2019087718C112887158 @default.
• W2019087718 hasConceptScore W2019087718C115624301 @default.
• W2019087718 hasConceptScore W2019087718C121332964 @default.
• W2019087718 hasConceptScore W2019087718C155355069 @default.
• W2019087718 hasConceptScore W2019087718C16889073 @default.
• W2019087718 hasConceptScore W2019087718C170751736 @default.
• W2019087718 hasConceptScore W2019087718C178790620 @default.
• W2019087718 hasConceptScore W2019087718C185592680 @default.
• W2019087718 hasConceptScore W2019087718C194196696 @default.
• W2019087718 hasConceptScore W2019087718C200119971 @default.
• W2019087718 hasConceptScore W2019087718C26873012 @default.
• W2019087718 hasConceptScore W2019087718C2775998212 @default.
• W2019087718 hasConceptScore W2019087718C2777854368 @default.
• W2019087718 hasConceptScore W2019087718C2778074193 @default.
• W2019087718 hasConceptScore W2019087718C32909587 @default.
• W2019087718 hasConceptScore W2019087718C544778455 @default.
• W2019087718 hasConceptScore W2019087718C61276311 @default.
• W2019087718 hasConceptScore W2019087718C71240020 @default.
• W2019087718 hasConceptScore W2019087718C8010536 @default.
• W2019087718 hasConceptScore W2019087718C92840921 @default.
• W2019087718 hasIssue "2" @default.
• W2019087718 hasLocation W20190877181 @default.
• W2019087718 hasOpenAccess W2019087718 @default.
• W2019087718 hasPrimaryLocation W20190877181 @default.
• W2019087718 hasRelatedWork W1988396436 @default.
• W2019087718 hasRelatedWork W2019087718 @default.
• W2019087718 hasRelatedWork W2077816857 @default.
• W2019087718 hasRelatedWork W2091437297 @default.
• W2019087718 hasRelatedWork W2314729056 @default.

• next