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- W2019111008 abstract "The complex [(κ2-P,N)-Ph2PCH2CH2NMe2]PtMe2 reacts with chlorinated hydrocarbons such as CCl4, CHCl3, CH2Cl2, and CH3Cl by oxidative addition of the C−Cl bond. In the reaction with CCl4, the complexes [(κ2-P,N)-Ph2PCH2CH2NMe2]Pt(Me)Cl, [(κ2-P,N)-Ph2PCH2CH2NMe2]Pt(Me)3Cl, and [(κ2-P,N)-Ph2PCH2CH2NMe2]Pt(CCl=CH2)Cl are obtained. The analogous P,P-chelated complex [(κ2-P,P)-Ph2CH2CH2PPh2]PtMe2 does not react under the same conditions. Reaction of [(κ2-P,N)-Ph2PCH2CH2NMe2]PtMe2 with ClSiMe2Ph results in the formation of Ph2Me4Si2 along with [(κ2-P,N)-Ph2PCH2CH2NMe2]Pt(Me)Cl and [(κ2-P,N)-Ph2PCH2CH2NMe2]Pt(Me)3Cl. (© Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002)" @default.
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- W2019111008 date "2002-09-01" @default.
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- W2019111008 title "C−Cl and Si−Cl Activation byP,N-Chelated PtII Complexes" @default.
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- W2019111008 doi "https://doi.org/10.1002/1099-0682(200209)2002:9<2305::aid-ejic2305>3.0.co;2-p" @default.
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