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- W2019123030 abstract "H 2 O 2 aerosol was used to oxidize dichlorvos vapor. 80.7% of dichlorvos, with the initial concentration of 90.9 mg/m 3 , was decontaminated when the H 2 O 2 concentration kept in the range of 110~130 mg/m 3 within 60 min. According to the oxidation products, analyzed by GC-MS, the decontamination reaction mechanism was discussed. Radical chain reaction is the main decontamination mechanism. H 2 O 2 is dissociated to HOO - , which can induce the formation of ·OH. The double bond in dichlorvos molecule is attacked by ·OH to form molecule radical, which is further oxidized to 1,1-dichloro ethoxy dimethyl phosphate, 1,1,1-trichloro-2-hydroxyl-ethyl dimethyl phosphate, dimethyl phosphite, dimethyl phosphate, trimethyl phosphate, methyl phosphate, dichloro acetaldehyde, oxalic acid, CH 2 Cl 2 , CHCl 3 , parts of which are mineralized to phosphoric acid, CO 2 , H 2 O and chloridion." @default.
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- W2019123030 date "2013-09-01" @default.
- W2019123030 modified "2023-09-25" @default.
- W2019123030 title "Decontamination of Dichlorvos by Hydrogen Peroxide" @default.
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- W2019123030 doi "https://doi.org/10.4028/www.scientific.net/amr.781-784.59" @default.
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