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- W2019135090 abstract "High resolution near infrared spectra of the two lowest frequency intermolecular modes in HF‐stretch excited states of (HF)2 have been characterized using a slit‐jet infrared spectrometer. In the spectral region surveyed, ten vibration–rotation–tunneling (VRT) bands are observed and assigned to the low frequency ‘‘van der Waals stretch’’ (ν4) and ‘‘geared bend’’ (ν5) intermolecular modes, in combination with either the hydrogen bond acceptor (ν1) or donor (ν2) high‐frequency intramolecular HF stretches. Analysis of the rotationally resolved spectra provide intermolecular frequencies, rotational constants, tunneling splittings, and predissociation rates for the ν4/ν5 intermolecular excited states. The intermolecular vibrational frequencies in the combination states display a systematic dependence on intramolecular redshift that allows far‐IR intermolecular frequencies to be reliably extrapolated from the near‐IR data. Approximately tenfold increases in the hydrogen bond interconversion tunneling splittings with either ν4 or ν5 excitation indicate that both intermolecular modes correlate strongly to the tunneling coordinate. The high resolution VRT line shapes reveal mode specific predissociation broadening sensitive predominantly to intramolecular excitation, with weaker but significant additional effects due to low frequency intermolecular excitation. Analysis of the high resolution spectroscopic data for these ν4 and ν5 combination bands suggests strong state mixing between what has previously been considered van der Waals stretch and geared bend degrees of freedom." @default.
- W2019135090 created "2016-06-24" @default.
- W2019135090 creator A5021481767 @default.
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- W2019135090 date "1996-04-22" @default.
- W2019135090 modified "2023-09-23" @default.
- W2019135090 title "Probing hydrogen bond potentials via combination band spectroscopy: A near infrared study of the geared bend/van der Waals stretch intermolecular modes in (HF)<sub>2</sub>" @default.
- W2019135090 cites W1963694171 @default.
- W2019135090 cites W1969359506 @default.
- W2019135090 cites W1969864319 @default.
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- W2019135090 cites W1970730636 @default.
- W2019135090 cites W1974860836 @default.
- W2019135090 cites W1975095425 @default.
- W2019135090 cites W1977222838 @default.
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- W2019135090 cites W1983822919 @default.
- W2019135090 cites W1986866131 @default.
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- W2019135090 cites W2016431095 @default.
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- W2019135090 doi "https://doi.org/10.1063/1.471285" @default.
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