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• W2019137071 abstract "The size and shape of the chiral cavity of a macrocyclic receptor were tuned by the alteration of the binaphthyl moiety to improve the chiral recognition/discrimination ability. For example, host 3 with the 3,5-bis(trifluoromethyl)phenyl group at the 3,3′-positions showed improved enantioselectivity for small molecules such as 2-chloropropionic acid and methyl lactate as evaluated by the binding constants. This host 3 also had an excellent ability as an NMR chiral solvating agent." @default.
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• W2019137071 date "2008-10-17" @default.
• W2019137071 modified "2023-10-18" @default.
• W2019137071 title "Tuning the Chiral Cavity of Macrocyclic Receptor for Chiral Recognition and Discrimination" @default.
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• W2019137071 doi "https://doi.org/10.1021/jo801584b" @default.
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