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- W2019144105 abstract "Abstract The isothermal section (500 °C) of the phase diagram of the Gd–Fe–Ga ternary system was investigated by X-ray powder diffraction analysis. Eleven binary compounds, GdGa 2 , GdGa, Gd 3 Ga 2 , Gd 5 Ga 3 , GdFe 2 , GdFe 3 , Gd 2 Fe 17 , Fe 3 Ga, Fe 6 Ga 5 , Fe 3 Ga 4 and FeGa 3 , have been confirmed. Two ternary compounds, GdFe 5.3 Ga 6.7 and GdFe 5 Ga 7 , were found in this ternary system at 500 °C. The compound GdFe 5.3 Ga 6.7 is orthorhombic ScFe 6 Ga 6 -type structure (space group Immm ) with a = 0.8567 (9), b = 0.86960 (9) and c = 0.50782 (5) nm, while the compound GdFe 5 Ga 7 is tetragonal ThMn 12 -type structure (space group I 4/ mmm ) with a = 0.8651(1) and c = 0.50934 (6) nm. The isothermal section at 500 °C consists of 16 single-phase regions, 31 two-phase regions and 16 three-phase regions. The maximum solid solubilities of Ga in GdFe 2 , GdFe 3 , Gd 2 Fe 17 are 9.2, 9.0, and 44.3 at.% respectively. The homogeneity range of GdGa 2 is from 22 to 33.3 at.% Ga in Gd–Ga side but the solid solubility of Fe in this compound is very small. The homogeneity range of GdFe 5 Ga 7 is from 53.8 to 59.2 at.% Ga. Very limited solid solutions were measured in the other compounds." @default.
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- W2019144105 date "2009-06-01" @default.
- W2019144105 modified "2023-09-25" @default.
- W2019144105 title "The phase relations in the Gd–Fe–Ga ternary system at 500°C" @default.
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- W2019144105 doi "https://doi.org/10.1016/j.jallcom.2008.12.057" @default.
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