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- W2019214458 abstract "Some surface aspects of the thermal and X-ray induced degradation of a cellulose nitrate have been studied by Electron Spectroscopy for Chemical Applications (ESCA). The degradation process in the surface regions during X-ray exposure involves a decrease in the nitrate concentration and results in the concomitant evolution of NOx. On extended exposure a further nitrogen functionality becomes evident by the appearance of a peak centred at ∼400 eV binding energy. The data obtained from the CIs envelopes indicate that the degradation mechanisms involve chain structure and the β-d-anhydroglucose ring. The surface degradation during the thermal treatment in air involves a slight decrease in nitrate concentration with no evidence for a low binding energy nitrogen signal. Examination of the CIs envelopes indicates no changes. Allusion is made to differences in the physical nature of these samples, and possible schematic pathways to degradation products are discussed." @default.
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- W2019214458 date "1985-01-01" @default.
- W2019214458 modified "2023-10-17" @default.
- W2019214458 title "ESCA studies of the thermal and X-ray induced degradation of cellulose nitrates" @default.
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