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- W2019222013 abstract "The first enantioselective syntheses of sulfur flavan-3-ol analogues 1-8 have been accomplished, whereby the oxygen atom of the pyran ring has been replaced by a sulfur atom. The key steps were: (a) Pd(0) catalyzed introduction of -S t-butyl group, (b) Sharpless enantioselective dihydroxylation of the alkene, (c) acid catalyzed ring closure to produce the thiopyran ring, and (d) removal of benzyl groups using N,N-dimethylaniline and AlCl(3). The compounds were isolated in high chemical and optical purity." @default.
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- W2019222013 date "2010-08-13" @default.
- W2019222013 modified "2023-09-25" @default.
- W2019222013 title "Enantioselctive Syntheses of Sulfur Analogues of Flavan-3-Ols" @default.
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- W2019222013 doi "https://doi.org/10.3390/molecules15085595" @default.
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