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- W2019238574 abstract "Chlorotris(triphenylphosphine)rhodium is a very effective and selective catalyst for the alcoholysis of diarylsilanes. Treatment with ethylenic alcohols leads in one step to 1-oxa-2-silacycloalcane. The alcoholysis of asymmetric organosilicon compounds proceeds predominantly with retention of configuration at the silicon atom. A mechanism is proposed to explain the experimental results. Le chlorotris(triphenylphosphine)rhodium est un catalyseur très efficace pour la réaction d'alcoolyse des organosilanes. Il permet la synthèse d'alcoxysilanes bifonctionnels avec une sélectivité totale. La réaction d'alcools éthyléniques permet en une seuleétape, d'accéder à des oxa-l-sila-2-cycloalcanes. L'alcoolyse d'organosilanes chiraux a lieu avec prédominance de rétention de configuration de l'atome de silicium. Un mécanisme est proposé pour rendre compte des résultats expérimentaux." @default.
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- W2019238574 date "1976-07-01" @default.
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- W2019238574 title "Alcoolyse selective d'organosilanes catalysee par un complexe du rhodium" @default.
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- W2019238574 doi "https://doi.org/10.1016/s0022-328x(00)87230-7" @default.
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