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- W2019248923 abstract "Abstract The reaction of Mo 3 OS 3 (dtp) 4 (H 2 O) (dtp=S 2 P(OC 2 H 5 ) 2 ) with CuI yielded the new trimolybdenum cluster [Mo 3 (μ 3 -X)(μ 2 -S 2 ) 3 (dtp) 3 I 3 ] (X=58%O+42%S). Crystal structure analysis showed that the compound has a [Mo 3 X(S 2 ) 3 ] 4+ cluster core, and the I 3 − group functions as a two-way coordinated ligand which links the three out-of-{Mo 3 } plane S atoms in the cluster core at one end (I–S∼3.3 A) and two adjacent trinuclear clusters at the other (I⋯S∼3.6 A), thus forming a [Mo 3 X(S 2 ) 3 ] cluster layer. The bonding features of the cluster characteristic of a semiconductor are demonstrated by energy band and density functional calculations." @default.
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- W2019248923 date "2000-04-01" @default.
- W2019248923 modified "2023-09-27" @default.
- W2019248923 title "Synthesis, crystal structure and bonding features of a trinuclear cluster [Mo3X(S2)3(dtp)3I3] (X=O,S) with layer-like packing" @default.
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