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- W2019253706 abstract "The reaction of sulfur dioxide (SO2) with 1-propanethiol (NPT), 2-propanethiol (IPT), or 2-methyl-2-propanethiol (TBT) catalyzed by boron trifluoride ethrate (BF3OEt2) was investigated. The ratios of dialkyl trisulfide to dialkyl disulfide obtained (RSSSR/RSSR) at an early stage of the reaction were larger than 1 for the reaction of TBT and less than 1 for the reaction of NPT or IPT. The reaction of dithiosulfites with BF3OEt2 in the presence or absence of thiol was investigated. From a consideration of the similarity of the composition of the sulfides formed in the reaction of dithiosulfites with BF3OEt2 to those in the reaction of SO2 with thiol in the presence of BF3OEt2, the possibility of the intervention of dithiosulfite as a reaction intermediate in the reaction of SO2 with thiol was discussed." @default.
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- W2019253706 date "1983-09-01" @default.
- W2019253706 modified "2023-09-25" @default.
- W2019253706 title "The Reaction of Sulfur Dioxide with Thiols Catalyzed by Boron Trifluoride Etherate. Evidence for a Possible Intervention of Dithiosulfite as a Reaction Intermediate" @default.
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- W2019253706 doi "https://doi.org/10.1246/bcsj.56.2657" @default.
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