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Matches in SemOpenAlex for { <https://semopenalex.org/work/W2019257468> ?p ?o ?g. }

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• W2019257468 abstract "The title compound, C 33 H 35 NO 6 [systematic name: ( Z )-3-(4-{( E )-[( E )-1a,5-dimethyl-9-oxo-2,3,7,7a-tetrahydrooxireno[2′,3′:9,10]cyclodeca[1,2- b ]furan-8(1a H ,6 H ,9 H ,10a H ,10b H )-ylidene]methyl}phenyl)-2-(3,4,5-trimethoxyphenyl)acrylonitrile methanol hemisolvate], C 33 H 35 NO 6 ·0.5CH 3 OH, was prepared by the reaction of ( Z )-3-(4-iodophenyl)-2-(3,4,5-trimethoxyphenyl)acrylonitrile with parthenolide [systematic name: ( E )-1a,5-dimethyl-8-methylene-2,3,6,7,7a,8,10a,10b-octahydrooxireno[2′,3′:9,10]cyclodeca[1,2- b ]furan-9(1a H )-one] under Heck reaction conditions. The molecule is built up from fused ten-, five- (lactone) and three-membered (epoxide) rings with a {4-[( Z )-2-cyano-2-(3,4,5-trimethoxyphenyl)ethenyl]phenyl}methylidene group as a substituent. The 4-[( Z )-2-cyano-2-(3,4,5-trimethoxyphenyl)ethenyl]phenyl group on the parthenolide exocyclic double bond is oriented in a trans position to the lactone ring to form the E isomer. The dihedral angle between the benzene ring of the phenyl moiety and the lactone ring mean plane is 21.93 (4)°." @default.
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• W2019257468 date "2014-09-06" @default.
• W2019257468 modified "2023-09-25" @default.
• W2019257468 title "Crystal structure of (<i>E</i>)-13-{4-[(<i>Z</i>)-2-cyano-2-(3,4,5-trimethoxyphenyl)ethenyl]phenyl}parthenolide methanol hemisolvate" @default.
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• W2019257468 doi "https://doi.org/10.1107/s1600536814019333" @default.
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