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• W2019294043 abstract "Experimental and theoretical results are presented on increases in the rate of electrochemical reactions, which are achieved by replacing a small fraction of the original anions in solution with more inhibiting ones. The rate of the electrochemical oxidation of formic acid was substantially increased by replacing a small amount of the supporting electrolyte, perchloric acid, with either sulfuric acid or tetrafluoroboric acid. The largest increases were achieved by substituting mixtures of the last two acids. A theoretical analysis of an electrochemical reaction coupled to anion adsorption is presented. The analysis reveals that, if repulsive forces of appropriate strength form between unlike surface anions, replacing a fraction of the original anions in solution with one or two kinds of more inhibiting anions can increase the rate of reaction." @default.
• W2019294043 created "2016-06-24" @default.
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• W2019294043 date "2006-02-21" @default.
• W2019294043 modified "2023-09-27" @default.
• W2019294043 title "An Experimental and Theoretical Study of Interactions between Unlike Surface Anions and Increases in the Rate of Electrochemical Reactions" @default.
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• W2019294043 doi "https://doi.org/10.1021/jp055843x" @default.
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