Matches in SemOpenAlex for { <https://semopenalex.org/work/W2019301667> ?p ?o ?g. }
Showing items 1 to 100 of
100
with 100 items per page.
- W2019301667 endingPage "78" @default.
- W2019301667 startingPage "74" @default.
- W2019301667 abstract "Ce 0.5 Zr 0.5 O 2 and γ-Al 2 O 3 supported nickel catalysts were investigated for CO 2 adsorption and methanation using in-situ FTIR spectroscopy. The reaction pathway on Ni/γ-Al 2 O 3 is similar to that on Ni/Ce 0.5 Zr 0.5 O 2 , only differing in reactive basic sites. CO 2 adsorption on medium basic sites of Ni/Ce 0.5 Zr 0.5 O 2 results in monodentate carbonates. CO 2 adsorbed on strong basic sites of Ni/γ-Al 2 O 3 will not participate in the reaction. It was assumed that monodentate formate derived from monodentate carbonate on medium basic sites, could be hydrogenated more quickly than bidentate formate derived from hydrogen carbonate. Medium basic sites were proposed to enhance CO 2 methanation activity. • CO 2 methanation mechanism is compared on Ni/Ce 0.5 Zr 0.5 O 2 and Ni/γ-Al 2 O 3 . • The only difference of the mechanism is the reactive basic sites. • Medium basic sites are proposed to promote the formation of monodentate formate. • Monodentate formate could be hydrogenated quickly compared with bidentate formate. • Medium basic sites are proposed to enhance the activity of CO 2 methanation." @default.
- W2019301667 created "2016-06-24" @default.
- W2019301667 creator A5024674833 @default.
- W2019301667 creator A5046484895 @default.
- W2019301667 creator A5047319926 @default.
- W2019301667 creator A5054265389 @default.
- W2019301667 date "2014-02-01" @default.
- W2019301667 modified "2023-10-13" @default.
- W2019301667 title "Insight into the reaction route of CO2 methanation: Promotion effect of medium basic sites" @default.
- W2019301667 cites W1974012028 @default.
- W2019301667 cites W1977690976 @default.
- W2019301667 cites W1980818619 @default.
- W2019301667 cites W1985997258 @default.
- W2019301667 cites W2007298640 @default.
- W2019301667 cites W2011098628 @default.
- W2019301667 cites W2013623339 @default.
- W2019301667 cites W2020275188 @default.
- W2019301667 cites W2022042730 @default.
- W2019301667 cites W2023213860 @default.
- W2019301667 cites W2028795666 @default.
- W2019301667 cites W2033955352 @default.
- W2019301667 cites W2053535968 @default.
- W2019301667 cites W2053927206 @default.
- W2019301667 cites W2057457710 @default.
- W2019301667 cites W2059715814 @default.
- W2019301667 cites W2063820341 @default.
- W2019301667 cites W2072304937 @default.
- W2019301667 cites W2076522263 @default.
- W2019301667 cites W2083573144 @default.
- W2019301667 cites W2086875421 @default.
- W2019301667 cites W2090447561 @default.
- W2019301667 cites W2090598655 @default.
- W2019301667 cites W2094116045 @default.
- W2019301667 cites W2114148697 @default.
- W2019301667 cites W2140902835 @default.
- W2019301667 cites W2322588385 @default.
- W2019301667 cites W6983100 @default.
- W2019301667 doi "https://doi.org/10.1016/j.catcom.2013.10.034" @default.
- W2019301667 hasPublicationYear "2014" @default.
- W2019301667 type Work @default.
- W2019301667 sameAs 2019301667 @default.
- W2019301667 citedByCount "340" @default.
- W2019301667 countsByYear W20193016672014 @default.
- W2019301667 countsByYear W20193016672015 @default.
- W2019301667 countsByYear W20193016672016 @default.
- W2019301667 countsByYear W20193016672017 @default.
- W2019301667 countsByYear W20193016672018 @default.
- W2019301667 countsByYear W20193016672019 @default.
- W2019301667 countsByYear W20193016672020 @default.
- W2019301667 countsByYear W20193016672021 @default.
- W2019301667 countsByYear W20193016672022 @default.
- W2019301667 countsByYear W20193016672023 @default.
- W2019301667 crossrefType "journal-article" @default.
- W2019301667 hasAuthorship W2019301667A5024674833 @default.
- W2019301667 hasAuthorship W2019301667A5046484895 @default.
- W2019301667 hasAuthorship W2019301667A5047319926 @default.
- W2019301667 hasAuthorship W2019301667A5054265389 @default.
- W2019301667 hasConcept C123703457 @default.
- W2019301667 hasConcept C150394285 @default.
- W2019301667 hasConcept C161790260 @default.
- W2019301667 hasConcept C178516000 @default.
- W2019301667 hasConcept C178790620 @default.
- W2019301667 hasConcept C179104552 @default.
- W2019301667 hasConcept C185592680 @default.
- W2019301667 hasConcept C2780178953 @default.
- W2019301667 hasConcept C2780659211 @default.
- W2019301667 hasConcept C504270822 @default.
- W2019301667 hasConcept C544153396 @default.
- W2019301667 hasConceptScore W2019301667C123703457 @default.
- W2019301667 hasConceptScore W2019301667C150394285 @default.
- W2019301667 hasConceptScore W2019301667C161790260 @default.
- W2019301667 hasConceptScore W2019301667C178516000 @default.
- W2019301667 hasConceptScore W2019301667C178790620 @default.
- W2019301667 hasConceptScore W2019301667C179104552 @default.
- W2019301667 hasConceptScore W2019301667C185592680 @default.
- W2019301667 hasConceptScore W2019301667C2780178953 @default.
- W2019301667 hasConceptScore W2019301667C2780659211 @default.
- W2019301667 hasConceptScore W2019301667C504270822 @default.
- W2019301667 hasConceptScore W2019301667C544153396 @default.
- W2019301667 hasFunder F4320321001 @default.
- W2019301667 hasLocation W20193016671 @default.
- W2019301667 hasOpenAccess W2019301667 @default.
- W2019301667 hasPrimaryLocation W20193016671 @default.
- W2019301667 hasRelatedWork W2075990793 @default.
- W2019301667 hasRelatedWork W2334975982 @default.
- W2019301667 hasRelatedWork W2348646062 @default.
- W2019301667 hasRelatedWork W2368933036 @default.
- W2019301667 hasRelatedWork W2375853005 @default.
- W2019301667 hasRelatedWork W2790498888 @default.
- W2019301667 hasRelatedWork W2810036863 @default.
- W2019301667 hasRelatedWork W2921724393 @default.
- W2019301667 hasRelatedWork W2922443046 @default.
- W2019301667 hasRelatedWork W3176935430 @default.
- W2019301667 hasVolume "45" @default.
- W2019301667 isParatext "false" @default.
- W2019301667 isRetracted "false" @default.
- W2019301667 magId "2019301667" @default.
- W2019301667 workType "article" @default.