FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2019302392> ?p ?o ?g. }

• W2019302392 endingPage "3717" @default.
• W2019302392 startingPage "3710" @default.
• W2019302392 abstract "Treatment of the iridacyclopentadiene complex (1, R = CO2CH3) with silver tetrafluoroborate, followed by addition of a terminal alkyne (ethyne, ethyl ethnynyl ether, methyl propargyl ether), yields iridium(III) aryl-hydride complexes (6-H, R1 = H; 6-OEt, R1 = OCH2CH3; 6-CH2OMe, R1 = CH2OCH3). The structure of 6-OEt was established by X-ray crystallographic analysis. Treatment of 6-H with either HCl or carbon monoxide results in demetalation to give tetramethyl 1,2,3,4-benzenetetracarboxylate [C6(CO2Me)4H2]. When 3-butyn-2-ol and propargyl alcohol are employed as substrates, a similar reaction occurs with 1/AgBF4 to produce the phthalimidyl complexes (7-H, R1 = H; 7-Me, R1 = CH3). The lactone ring in 7 is generated from an intramolecular transesterification of the hydroxyl with an adjacent methyl ester. In all cases these products are attributed to tandem cycloaromatization and orthometalation processes." @default.
• W2019302392 created "2016-06-24" @default.
• W2019302392 creator A5026822611 @default.
• W2019302392 creator A5040522842 @default.
• W2019302392 creator A5041616647 @default.
• W2019302392 creator A5048478689 @default.
• W2019302392 creator A5070585908 @default.
• W2019302392 creator A5089581111 @default.
• W2019302392 date "2001-07-17" @default.
• W2019302392 modified "2023-09-27" @default.
• W2019302392 title "Iridacyclopentadiene Reactions with Terminal Alkynes: Tandem Cycloaromatization and Orthometalation" @default.
• W2019302392 cites W1974312971 @default.
• W2019302392 cites W1977930210 @default.
• W2019302392 cites W1985724157 @default.
• W2019302392 cites W1986964608 @default.
• W2019302392 cites W1988433908 @default.
• W2019302392 cites W2000028230 @default.
• W2019302392 cites W2007329050 @default.
• W2019302392 cites W2017033936 @default.
• W2019302392 cites W2024839840 @default.
• W2019302392 cites W2029259254 @default.
• W2019302392 cites W2042962421 @default.
• W2019302392 cites W2046229055 @default.
• W2019302392 cites W2055916630 @default.
• W2019302392 cites W2056585261 @default.
• W2019302392 cites W2068447225 @default.
• W2019302392 cites W2092314846 @default.
• W2019302392 cites W2094688967 @default.
• W2019302392 cites W2124545509 @default.
• W2019302392 cites W2949413844 @default.
• W2019302392 cites W2951641387 @default.
• W2019302392 doi "https://doi.org/10.1021/om0102450" @default.
• W2019302392 hasPublicationYear "2001" @default.
• W2019302392 type Work @default.
• W2019302392 sameAs 2019302392 @default.
• W2019302392 citedByCount "37" @default.
• W2019302392 countsByYear W20193023922012 @default.
• W2019302392 countsByYear W20193023922013 @default.
• W2019302392 countsByYear W20193023922014 @default.
• W2019302392 countsByYear W20193023922015 @default.
• W2019302392 countsByYear W20193023922016 @default.
• W2019302392 countsByYear W20193023922019 @default.
• W2019302392 countsByYear W20193023922020 @default.
• W2019302392 countsByYear W20193023922023 @default.
• W2019302392 crossrefType "journal-article" @default.
• W2019302392 hasAuthorship W2019302392A5026822611 @default.
• W2019302392 hasAuthorship W2019302392A5040522842 @default.
• W2019302392 hasAuthorship W2019302392A5041616647 @default.
• W2019302392 hasAuthorship W2019302392A5048478689 @default.
• W2019302392 hasAuthorship W2019302392A5070585908 @default.
• W2019302392 hasAuthorship W2019302392A5089581111 @default.
• W2019302392 hasConcept C154881586 @default.
• W2019302392 hasConcept C155647269 @default.
• W2019302392 hasConcept C159985019 @default.
• W2019302392 hasConcept C161790260 @default.
• W2019302392 hasConcept C178790620 @default.
• W2019302392 hasConcept C185592680 @default.
• W2019302392 hasConcept C192562407 @default.
• W2019302392 hasConcept C2777731188 @default.
• W2019302392 hasConcept C2777814067 @default.
• W2019302392 hasConcept C2777961443 @default.
• W2019302392 hasConcept C2779012754 @default.
• W2019302392 hasConcept C2780263894 @default.
• W2019302392 hasConcept C2780378348 @default.
• W2019302392 hasConcept C2780407432 @default.
• W2019302392 hasConcept C2780437523 @default.
• W2019302392 hasConcept C2780872544 @default.
• W2019302392 hasConcept C2781076698 @default.
• W2019302392 hasConcept C512968161 @default.
• W2019302392 hasConcept C528581852 @default.
• W2019302392 hasConcept C71240020 @default.
• W2019302392 hasConcept C75079739 @default.
• W2019302392 hasConceptScore W2019302392C154881586 @default.
• W2019302392 hasConceptScore W2019302392C155647269 @default.
• W2019302392 hasConceptScore W2019302392C159985019 @default.
• W2019302392 hasConceptScore W2019302392C161790260 @default.
• W2019302392 hasConceptScore W2019302392C178790620 @default.
• W2019302392 hasConceptScore W2019302392C185592680 @default.
• W2019302392 hasConceptScore W2019302392C192562407 @default.
• W2019302392 hasConceptScore W2019302392C2777731188 @default.
• W2019302392 hasConceptScore W2019302392C2777814067 @default.
• W2019302392 hasConceptScore W2019302392C2777961443 @default.
• W2019302392 hasConceptScore W2019302392C2779012754 @default.
• W2019302392 hasConceptScore W2019302392C2780263894 @default.
• W2019302392 hasConceptScore W2019302392C2780378348 @default.
• W2019302392 hasConceptScore W2019302392C2780407432 @default.
• W2019302392 hasConceptScore W2019302392C2780437523 @default.
• W2019302392 hasConceptScore W2019302392C2780872544 @default.
• W2019302392 hasConceptScore W2019302392C2781076698 @default.
• W2019302392 hasConceptScore W2019302392C512968161 @default.
• W2019302392 hasConceptScore W2019302392C528581852 @default.
• W2019302392 hasConceptScore W2019302392C71240020 @default.
• W2019302392 hasConceptScore W2019302392C75079739 @default.
• W2019302392 hasIssue "17" @default.
• W2019302392 hasLocation W20193023921 @default.
• W2019302392 hasOpenAccess W2019302392 @default.
• W2019302392 hasPrimaryLocation W20193023921 @default.
• W2019302392 hasRelatedWork W1847179247 @default.

• next