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- W2019304639 abstract "Substituted α,β-unsaturated ketones were selectively reduced to the corresponding allylic alcohols under mild reaction conditions. The allylic alcohols thus obtained were kinetically resolved by lipase catalyzed transesterification in the same pot to afford chiral allylic alcohols in excellent enantioselectivity. Various lipases were screened for this one-pot transesterification of allylic alcohols. Effects of different solvent have also been studied under these conditions. Pseudomonas cepacia lipase immobilized on ceramic particles (PS-C) and on diatomaceous earth (PS-D) catalyzes this transesterification in diisopropyl ether in a highly efficient manner." @default.
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- W2019304639 date "2003-09-01" @default.
- W2019304639 modified "2023-10-13" @default.
- W2019304639 title "One-pot synthesis and resolution of chiral allylic alcohols" @default.
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- W2019304639 doi "https://doi.org/10.1016/s0957-4166(03)00598-6" @default.
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