Matches in SemOpenAlex for { <https://semopenalex.org/work/W2019326476> ?p ?o ?g. }
- W2019326476 endingPage "7570" @default.
- W2019326476 startingPage "7562" @default.
- W2019326476 abstract "Abstract A new class of homologous gelators, LG 12 ‐(CH 2 ) n ‐BSA, composed of bipyridinyl groups, L ‐glutamic moieties having double dodecyl chains, and linked alkyl spacers with different lengths were synthesized. It was found that these gelators could immobilize medium‐polarity solvents readily and the behaviors of these gels showed a dependence on the spacer length. Of all the gels, the LG 12 ‐(CH 2 ) 11 ‐BSA gels exhibited self‐healing property and multiple‐stimulus responsibility, such as heating, shaking, and sonication. The investigation of CD spectra indicated that the supramolecular chirality, which was attributed to the chiral transfer from the chiral center to the assemblies, was also closely related to the length of methylene spacers. The longer the alkyl spacers, the weaker the transmitted supramolecular chirality. Only LG 12 ‐(CH 2 ) 1 ‐BSA gelators, which had the shortest spacers, formed right‐handed nanoscale chiral twists owing to crowded hydrogen bonding interactions. Moreover, the high‐polarity solvent DMF was found to be able to regulate the chiral twist as well as its pitch length readily." @default.
- W2019326476 created "2016-06-24" @default.
- W2019326476 creator A5030722635 @default.
- W2019326476 creator A5058453644 @default.
- W2019326476 creator A5066803271 @default.
- W2019326476 date "2015-04-01" @default.
- W2019326476 modified "2023-10-18" @default.
- W2019326476 title "Multiple-Stimulus-Responsive Supramolecular Gels and Regulation of Chiral Twists: The Effect of Spacer Length" @default.
- W2019326476 cites W1965030475 @default.
- W2019326476 cites W1967334144 @default.
- W2019326476 cites W1972449167 @default.
- W2019326476 cites W1974896454 @default.
- W2019326476 cites W1977204443 @default.
- W2019326476 cites W1985828623 @default.
- W2019326476 cites W1989812578 @default.
- W2019326476 cites W1995958134 @default.
- W2019326476 cites W1996479647 @default.
- W2019326476 cites W1998466839 @default.
- W2019326476 cites W1998506213 @default.
- W2019326476 cites W1999868778 @default.
- W2019326476 cites W2000357750 @default.
- W2019326476 cites W2000667216 @default.
- W2019326476 cites W2001280589 @default.
- W2019326476 cites W2003112024 @default.
- W2019326476 cites W2004550186 @default.
- W2019326476 cites W2004664828 @default.
- W2019326476 cites W2007113543 @default.
- W2019326476 cites W2007525977 @default.
- W2019326476 cites W2009842982 @default.
- W2019326476 cites W2017734059 @default.
- W2019326476 cites W2019945115 @default.
- W2019326476 cites W2022261188 @default.
- W2019326476 cites W2024965955 @default.
- W2019326476 cites W2027134315 @default.
- W2019326476 cites W2032751256 @default.
- W2019326476 cites W2034879681 @default.
- W2019326476 cites W2035191352 @default.
- W2019326476 cites W2038640962 @default.
- W2019326476 cites W2042048832 @default.
- W2019326476 cites W2042149157 @default.
- W2019326476 cites W2043485398 @default.
- W2019326476 cites W2046650105 @default.
- W2019326476 cites W2047283501 @default.
- W2019326476 cites W2048854490 @default.
- W2019326476 cites W2050624645 @default.
- W2019326476 cites W2053048760 @default.
- W2019326476 cites W2057026947 @default.
- W2019326476 cites W2057471218 @default.
- W2019326476 cites W2060022677 @default.
- W2019326476 cites W2060697331 @default.
- W2019326476 cites W2066146371 @default.
- W2019326476 cites W2067823628 @default.
- W2019326476 cites W2072159810 @default.
- W2019326476 cites W2074070959 @default.
- W2019326476 cites W2075185321 @default.
- W2019326476 cites W2075674313 @default.
- W2019326476 cites W2076093959 @default.
- W2019326476 cites W2080472241 @default.
- W2019326476 cites W2083064937 @default.
- W2019326476 cites W2083779691 @default.
- W2019326476 cites W2088448211 @default.
- W2019326476 cites W2090937254 @default.
- W2019326476 cites W2091220093 @default.
- W2019326476 cites W2092458550 @default.
- W2019326476 cites W2093421375 @default.
- W2019326476 cites W2094224265 @default.
- W2019326476 cites W2097228925 @default.
- W2019326476 cites W2098267590 @default.
- W2019326476 cites W2098618571 @default.
- W2019326476 cites W2099762355 @default.
- W2019326476 cites W2101809968 @default.
- W2019326476 cites W2102279271 @default.
- W2019326476 cites W2107602208 @default.
- W2019326476 cites W2111795271 @default.
- W2019326476 cites W2120188084 @default.
- W2019326476 cites W2120829433 @default.
- W2019326476 cites W2121833051 @default.
- W2019326476 cites W2124207597 @default.
- W2019326476 cites W2124662786 @default.
- W2019326476 cites W2125735347 @default.
- W2019326476 cites W2131999687 @default.
- W2019326476 cites W2133378893 @default.
- W2019326476 cites W2135533106 @default.
- W2019326476 cites W2137198445 @default.
- W2019326476 cites W2138946596 @default.
- W2019326476 cites W2148950728 @default.
- W2019326476 cites W2150721205 @default.
- W2019326476 cites W2150932805 @default.
- W2019326476 cites W2154356137 @default.
- W2019326476 cites W2161174878 @default.
- W2019326476 cites W2162777719 @default.
- W2019326476 cites W2163884416 @default.
- W2019326476 cites W2166086431 @default.
- W2019326476 cites W2169574205 @default.
- W2019326476 cites W2171139693 @default.
- W2019326476 cites W2172194132 @default.
- W2019326476 cites W2313209844 @default.
- W2019326476 cites W2314970156 @default.