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• W2019352282 abstract "Amorphous films in the systems AlPO4RO (R ≡ MgorCa) were prepared by r.f.-sputtering, and their densities, IR absorption spectra, and aluminum K-band X-ray emission spectra were determined to investigate the network structure. Furthermore, amorphous films of SiO2CaO were prepared in order to contrast the AlPO4-RO and SiO2RO systems. The density of the amorphous AlPO4RO and SiO2RO films increased monotonically with increasing RO content. The dependence on composition of the molar volume of AlPO4MgO films was very similar to that of SiO2MgO films. In contrast, in AlPO4CaO films the volume change was different from that in the SiO2CaO films. The results of the IR spectra and X-ray emission spectra indicate that the network structure of the amorphous AlPO4MgO films is composed of AlO4PO4 connecting tetrahedral dimers, which are the structural units of amorphous AlPO4 film. In the AlPO4CaO films, the AlO4PO4 dimers are decomposed into types of AlO4 tetrahedra different from those in the dimers, and the end PO3 groups." @default.
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• W2019352282 date "1993-05-01" @default.
• W2019352282 modified "2023-10-18" @default.
• W2019352282 title "Network structure of r.f.-sputtered amorphous AlPO4MgO and AlPO4CaO films" @default.
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• W2019352282 doi "https://doi.org/10.1016/0040-6090(93)90030-s" @default.
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