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• W2019362318 endingPage "1039" @default.
• W2019362318 startingPage "1035" @default.
• W2019362318 abstract "Powder samples and single crystals of the ternary oxide Ce3MoO7 were obtained by solid state reaction. The structure was determined by single-crystal X-ray diffraction. Ce3MoO7 crystallizes in the orthorhombic space group P212121 (no. 19) with unit-cell parameters a=7.5395(2) Å, b=7.6769(1) Å, c=10.9769(2) Å and Z=4. Full-matrix least-squares refinement on F2 using 3903 independent reflections for 101 refinable parameters results in R1=0.0281 and wR2=0.0473. The structure consists of chains of corner-linked MoO6 octahedra running parallel to the b-axis and separated from each other by seven- or eight-coordinate Ce–O polyhedra. The trend of the unit-cell parameters of the Ln3MoO7 series, plotted versus the R3+ ionic radius, shows a linear behavior, which strongly suggests a trivalent state for the Ce atoms. Magnetic susceptibility measurements confirm that the oxidation state of the Ce atoms is +3. Resistivity measurements on a single crystal show that the Ce3MoO7 compound is a semi-conductor with a band gap of about 2 eV." @default.
• W2019362318 created "2016-06-24" @default.
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• W2019362318 date "2009-05-01" @default.
• W2019362318 modified "2023-10-16" @default.
• W2019362318 title "Synthesis, crystal structure, and electrical and magnetic properties of Ce3MoO7" @default.
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• W2019362318 doi "https://doi.org/10.1016/j.jssc.2009.01.038" @default.
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