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- W2019369344 abstract "Abstract Rate constants for several intermediate steps in the OH‐initiated oxidation of isoprene were determined using laser‐photolysis/laser‐induced fluorescence of OH radicals at total pressures between 3 and 4 Torr at 295 K. The rate constant for decomposition of the hydroxyalkoxy radical was determined to be (3.0 ± 0.5) × 10 4 s −1 in this pressure range, which is in fair agreement with previous work. The presence of a prompt alkoxy decomposition pathway was also investigated and found to contribute less than 10% to the total hydroxyalkoxy radical decomposition. The rate constant for the reaction of the hydroxyperoxy radical with NO was determined to be (2.5 ± 0.5) × 10 −11 cm 3 molecule −1 s −1 , which is moderately higher than previously reported. © 2002 Wiley Periodicals, Inc. Int J Chem Kinet 34: 255–261, 2002" @default.
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- W2019369344 date "2002-02-26" @default.
- W2019369344 modified "2023-10-10" @default.
- W2019369344 title "The fate of the hydroxyalkoxy radical in the OH-initiated oxidation of isoprene" @default.
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- W2019369344 doi "https://doi.org/10.1002/kin.10050" @default.
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