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- W2019371915 abstract "Abstract The cis / trans isomerization of the bridging methylene complex {(μ-CH2)(μ-CO)[η5-C5H5-Fe(CO)]2} was studied in solution by 1H NMR spectrometry, using solvents with different polarities (acetone-d6, chloroform-d1 and benzene-d6). Equilibrium constants and rate constants for the forward and reverse steps were measured between 278 and 323 k. Both reactions show first-order kinetics. A possible mechanism for the isomerization is proposed, involving the breaking of a FeFe bond in the rate-determining step." @default.
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- W2019371915 date "1986-06-01" @default.
- W2019371915 modified "2023-09-24" @default.
- W2019371915 title "1H NMR study of the reversible cis / trans isomerization of {(μ-CH2)(μ-CO)[η5-C5H5Fe(CO)]2}" @default.
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- W2019371915 doi "https://doi.org/10.1016/s0022-328x(00)98999-x" @default.
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