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• W2019402018 abstract "A computer simulation program based on the density-matrix formalism for simulation of exchanged-broadened ESR spectra is described. The program is applicable to all intra- and intermolecular exchange reactions in all rate regions. The Lionville representation of the theory is also discussed. With this program the rate constants of some homogeneous electron self-exchange reactions of various quinones and vitamins are determined in the so-called “medium” exchange region. The rate constants are in the region of 2.7–31.0 × 108 M−1 s−1 and the δH‡ values are between 15.0 and 22.9 kJ/mol. The δS‡ values are negative for all systems. A thermostated flow electrolysis cell for intra muros radical generation is described." @default.
• W2019402018 created "2016-06-24" @default.
• W2019402018 creator A5057685944 @default.
• W2019402018 creator A5064835622 @default.
• W2019402018 date "1986-10-01" @default.
• W2019402018 modified "2023-10-12" @default.
• W2019402018 title "Application of the density-matrix formalism to the simulation of kinetic ESR spectra of intermolecular electron-transfer reactions" @default.
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• W2019402018 doi "https://doi.org/10.1016/0022-2364(86)90358-6" @default.
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