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- W2019402079 abstract "The lowest excited triplet 3bpy* has been found to be the principal transient species with a quantum yield of 0.83 in the 248 nm laser flash photolysis of 2,2′-bipyridine (bpy) in cyclohexane. The transient absorbs in the UV and blue region with λmax = 355 nm. The molar absorbance ϵ of the transient 3bpy* at 355 nm has been determined to be 53 600 ± 2100 M−1 cm−1. In deaerated solutions 3bpy* has been found to decay by mixed first-order and second-order kinetics with rate constants of 1.33 X 104 s−1 and 3.34 X 1010 M−1 s−1 respectively. It has also been found that the transient is scavenged by oxygen with a rate constant of 5.19 X 108 M−1 s−1. Some of the end-products of photolysis have been identified and a reaction mechanism is proposed." @default.
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- W2019402079 date "1988-05-01" @default.
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- W2019402079 title "Laser flash photolysis of 2,2′-bipyridine solution in cyclohexane" @default.
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- W2019402079 doi "https://doi.org/10.1016/1010-6030(88)80010-8" @default.
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