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- W2019403724 abstract "We present a new approach to the theory of intermediate valence, applicable to a specific kind of such solids. It consist of: (i) diagonalization of all intra-atomic terms in the Hamiltonian, including hybridization; (ii) elimination by means of a projection of all states beyond a low-energy manifold; (iii) conversion of the remaining states into equivalent fermion states; (iv) expression of the intra- and interatomic states in terms of the new fermion operators; and (v) treatment of this new Hamiltonian in a mean-field approximation. This approach, although valid in restricted cases, avoids all the problems of the alternative treatments." @default.
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- W2019403724 date "1979-12-01" @default.
- W2019403724 modified "2023-10-09" @default.
- W2019403724 title "New approach to the theory of intermediate valence. I. General formulation" @default.
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- W2019403724 doi "https://doi.org/10.1103/physrevb.20.4554" @default.
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