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- W2019413248 abstract "Kinetics of the isothermal solid state decomposition of the tris (2,2′-bipyridine) complexes of the first row transition group elements [M(bipy)3]Br2† (M Mn2+, Fe2+, Co2+, Ni2+, Cu2+ and Zn2+) were studied under vacuum using a weight loss method. Decomposition of [Fe(bipy)3]Br2, [Ni(bipy)3] Br2 and [Cu(bipy)3]Br2 were found to obey the Prout and Tomkins' rate equation, dα/dt = kα(1 − α). For the rest of the compounds the data were not reproducible enough to permit a definite conclusion. The activation energies for the first dissociation step of the complexes of Fe2+, Ni2+ and Cu2+ are given as is also a study of their decomposition products." @default.
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- W2019413248 title "Thermal decomposition of the tris (2,2′-bipyridine) complexes of some first row transition group elements in the solid state" @default.
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- W2019413248 doi "https://doi.org/10.1016/0022-1902(63)80206-7" @default.
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