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- W2019417657 abstract "Stability constants for complex formation between α-cyclodextrin and some ortho-, meta-, and para-disubstituted benzenes were measured in aqueous solution at 25°C by potentiometry, spectrophotometry, competitive spectrophotometry, and solubility. All systems form 1:1 complexes, some para substrates form 1:2 complexes (one substrate to two cyclodextrins), but no meta substrates form 1:2 complexes. Ortho substrates form weak complexes. These observations are accounted for in terms of a binding site molecular model. On the average over many systems, K11 (para) and K11 (meta) are approximately equal. Major discrepancies (greater than a factor of two) are diagnostic of significantly different electronic or steric effects in the complexing abilities of the isomeric substrates." @default.
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- W2019417657 title "Complexes of disubstituted benzene positional isomers with α-cyclodextrin" @default.
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- W2019417657 doi "https://doi.org/10.1016/0045-2068(85)90017-3" @default.
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