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- W2019418706 abstract "An x-ray structural analysis on cerium under pressure was made in order to investigate its valence behavior in the metallic state. A new form, ${ensuremath{alpha}}^{ensuremath{'}}ensuremath{-}mathrm{Ce}$, always fcc but strongly collapsed, was found to exist at pressures higher than 50 kbar. It was deduced that Ce is tetravalent in the ${ensuremath{alpha}}^{ensuremath{'}}$ form. The atomic radius of ${mathrm{Ce}}^{mathrm{IV}}$ was calculated, and the probable values of the valency in $ensuremath{gamma}ensuremath{-}mathrm{Ce}$ and $ensuremath{alpha}ensuremath{-}mathrm{Ce}$ are also estimated." @default.
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- W2019418706 date "1969-06-16" @default.
- W2019418706 modified "2023-09-27" @default.
- W2019418706 title "A New Allotropic form of Cerium Due to its Transition Under Pressure to the Tetravalent State" @default.
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- W2019418706 doi "https://doi.org/10.1103/physrevlett.22.1299" @default.
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