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- W2019419501 abstract "Abstract Hydrothermal growth, recrystallization and synthesis of α-TeO 2 . Te 6 O 11 C 12 , CuBr, PbI 2 , PbBr 2 , PbCl 2 SbNbO 4 monocrystals in an apparatus with visual examination are considered. In the apparatus with an optical quartz reactor the experiments were carried out to study the hydrodynamics of the solution in the homogenous and binary phase gas-liquid media. The data obtained agree well with those calculated thus permitting us to take into account the effect of hydrodynamical environment on supersaturation and mass transport kinetics. This fact was demonstrated while studying kinetics of mass transport of α-TeO 2 on seeds in homogenous and binary phase gas liquid media. Solubility of TeO 2 monocrystals and kinetic properties of their growth were studied in their dependences on physical, chemical and hydrodynamical parameters and the growth mechanism was suggested. Simultaneous growth of tellurium dioxide and oxychloride monocrystals was first observed in the system TeO 2 -HCl-H 2 O in homogenous and binary phase solutions, the corresponding dependences on temperature, temperature gradient and HCl concentration have been analyzed. The mechanism of simultaneous growth of these crystals and its relationship with the composition of the crystallization medium are considered. The apparatus with visual examination was demonstrated to be useful in the synthesis and recrystallization of PbHal (Hal = I, Br, Cl) monocrystals under various PT conditions." @default.
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- W2019419501 date "1991-01-01" @default.
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- W2019419501 title "Hydrothermal growth of crystals under visual examination" @default.
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- W2019419501 doi "https://doi.org/10.1016/0960-8974(91)90015-5" @default.
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