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- W2019428525 abstract "Preliminary results of restoring potentials of interactions Na(3s, 3p)-CO<SUB>2</SUB>(X<SUP>1</SUP>(Sigma) <SUB>g</SUB><SUP>+</SUP>) from measured far wing spectra of sodium resonance line Na-D perturbed by CO<SUB>2</SUB> are presented. The spectra in the range of (Delta) (sigma) approximately equals 10-3500 cm<SUP>-1</SUP> are considered following the quasi-static theory of line broadening by inert gases as continua and due to the A $ARLR X and B $ARLR X transitions of Na-CO<SUB>2</SUB> quasi-molecules. The reduced absorption coefficient K((sigma) ) at frequency (sigma) equals (sigma) <SUB>0</SUB> + (Delta) (sigma) is calculated as corresponding to the radiation from molecules with internuclear separation R, where hc(sigma) equals V<SUP>A,B</SUP> - V<SUP>X</SUP>. As a first approximation, all the three potentials are presented in the shape of a (6,12)-Lennard-Jones potential. The constants C<SUB>6</SUB> and C<SUB>12</SUB> are determined as independent variables by minimization of the sum of squared deviations between measured and calculated K((sigma) ). Four versions of minimization were considered successively: (1) only red wing, (2) only blue wing (3) both blue and red wings with 6 independent variables (C<SUB>6</SUB> and C<SUB>12</SUB>), and (4) both wings with fixed C<SUB>6</SUB>. The calculated K((Delta) (sigma) ) are compared to the measured ones." @default.
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- W2019428525 date "1996-12-27" @default.
- W2019428525 modified "2023-09-27" @default.
- W2019428525 title "<title>Restoring excited particle interaction potentials from laser spectroscopy data: Na broadened by CO2 as an example</title>" @default.
- W2019428525 doi "https://doi.org/10.1117/12.262940" @default.
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